Chemistry Labs

Problem 1

131I^{131}\ce{I} is a radioactive isotope of iodine (a β−\beta^{-} emitter) used in nuclear medicine for scintigraphy of thyroid disorders. Its decay rate constant is k=9.93×10−7 s−1k = 9.93\times10^{-7}\ \mathrm{s^{-1}}. (1.1) Write the decay reaction of 131I^{131}\ce{I}. (1.2) Calculate the half-life of 131I^{131}\ce{I} in days. (1.3) Calculate the time (in days) needed for a sample of 131I^{131}\ce{I} to fall to 30 % of its initial activity. (1.4) A Geiger counter detects activities of order 10−4 μ10^{-4}\ \muCi; calculate the minimum mass (in grams) of 131I^{131}\ce{I} detectable by this counter. (1 curie is the amount of a radioisotope producing 3.7×10103.7\times10^{10} disintegrations per second.)
Step 1 of 4: Decay equation
53131I→54131Xe+β−{}^{131}_{53}\ce{I} \rightarrow {}^{131}_{54}\ce{Xe} + \beta^{-}
Analysis

A β−\beta^- emission converts a neutron into a proton: the mass number stays 131 and the atomic number rises from 53 (I) to 54 (Xe).