Chemistry Labs

Problem 1

131I^{131}\ce{I} is a radioactive isotope of iodine (a β−\beta^{-} emitter) used in nuclear medicine for scintigraphy of thyroid disorders. Its decay rate constant is k=9.93×10−7 s−1k = 9.93\times10^{-7}\ \mathrm{s^{-1}}. (1.1) Write the decay reaction of 131I^{131}\ce{I}. (1.2) Calculate the half-life of 131I^{131}\ce{I} in days. (1.3) Calculate the time (in days) needed for a sample of 131I^{131}\ce{I} to fall to 30 % of its initial activity. (1.4) A Geiger counter detects activities of order 10−4 μ10^{-4}\ \muCi; calculate the minimum mass (in grams) of 131I^{131}\ce{I} detectable by this counter. (1 curie is the amount of a radioisotope producing 3.7×10103.7\times10^{10} disintegrations per second.)
Step 3 of 4: Time to 30 % activity
t=1kln⁡A0A=ln⁡(100/30)9.93×10−7=1.21×106 s=14.0 dt = \frac{1}{k}\ln\frac{A_0}{A} = \frac{\ln(100/30)}{9.93\times10^{-7}} = 1.21\times10^{6}\ \mathrm{s} = 14.0\ \mathrm{d}
Analysis

Activity is proportional to N, so A/A0=e−ktA/A_0 = e^{-kt}; solving t=ln⁡(1/0.30)/kt = \ln(1/0.30)/k gives 1.21×1061.21\times10^{6} s ≈ 14.0 days.