Problem 2

Astatine is the rarest naturally occurring element in the Earth's crust, with a total estimated mass of 30 g at any point in time; assume all astatine is the most stable naturally occurring isotope

^{219}

At. (a) Estimate how many At atoms occur naturally on Earth at any point in time. (b) Bismuth, obtained as a by-product of lead purification, is concentrated by adding magnesium and calcium to a lead–bismuth mixture; bismuth forms alloy A containing 7.91 % Ca and 9.60 % Mg by mass, with no lead. Determine the empirical formula of alloy A. (c) Alloy A reacts with chlorine gas to form bismuth and two ionic compounds B and C in a 2:1 ratio. Write the formulae of B and C. (d) Astatine is made by bombarding

^{209}_{83}

Bi with

\alpha

particles; the nuclei fuse to form

^{x}_{y}

At and two neutrons. Write the mass and atomic numbers of the astatine isotope. (e) Excess bismuth is removed with concentrated nitric acid, forming bismuth(III) nitrate, water and a colourless gas of molar mass 30.01 g mol

^{-1}

. Write the equation. (f) BrAt is made in two steps:

\ce{Br2}

reacts with D to give only E, and E reacts with

\ce{At2}

to give BrAt and D; the mass spectrum of E shows two major peaks of nearly equal intensity at m/z 205.82 and 207.82. Write the formulae of D and E. (g) 3.60 g of BrAt is synthesised; the half-life of this At isotope is 433 minutes. How long (to the nearest hour) until only 3.65 mg of BrAt remains?

Step 4 of 5: Nitric acid reaction and interhalogen

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\ce{Bi + 4HNO3 -> Bi(NO3)3 + 2H2O + NO};\quad \text{E} = \ce{BrI},\ \text{D} = \ce{I2}

Analysis

The 30.01 g mol $^{-1}$ colourless gas is NO. The nearly equal peaks at 205.82 and 207.82 correspond to $\ce{^{79}Br^{127}I}$ and $\ce{^{81}Br^{127}I}$ (Br isotopes ~50:50), so E is BrI and D is $\ce{I2}$ : $\ce{Br2 + I2 -> 2BrI}$ , then $\ce{2BrI + At2 -> 2BrAt + I2}$ .