Chemistry Labs
Undergraduate · 20 min

Criticality: how a fission chain grows or dies

Track the neutron population generation by generation for three values of the multiplication factor k and discover what “critical” really means.

Goal

Define the neutron multiplication factor k, predict the long-term fate of a chain for any k, and link k to reactor control.

Apparatus and reagents

A fissile sample of X235X22235U\ce{^{235}U} modelled as a neutron population multiplying by k each generation.

Procedure

  1. Start with k = 0.80 and follow the curve: count the generations needed for the population to fall below one neutron.
  2. Switch to k = 1.00: the population is flat. This is a controlled reactor — each fission triggers exactly one more.
  3. Switch to k = 1.25 and read the markers at generations 5 and 10; extrapolate what happens by generation 45.
  4. Estimate how long a real generation lasts (~10⁻⁸ s for prompt neutrons) and judge why a supercritical excursion is uncontrollable without engineered feedback.

What to observe

  • k < 1 gives geometric decay (Nn=N0knN_n = N_0 k^n): the chain self-extinguishes however large the sample.
  • k = 1 exactly holds the population constant; even k = 1.01 grows without bound — criticality is a razor’s edge.
  • At k = 1.25 the population multiplies by ~25000 in 45 generations — in real time that is microseconds.

Explanation

Fission of X235X22235U\ce{^{235}U} by a neutron yields two fragments plus on average 2.4 neutrons. Whether a chain survives is set by k, the average number of neutrons from one fission that cause another: some escape the sample, some are captured in 238U^{238}\ce{U} or the moderator. Enriching the fuel, shaping the geometry (critical mass) and absorbing excess neutrons with control rods all act on k. In reactors, delayed neutrons (~0.7 % of the yield) stretch the effective generation time, which is what makes k ≈ 1 controllable at all.

Chemists behind it

Related topics

Virtual experiment: a simplified model to build intuition. It does not replace real lab work or safety training; never repeat chemistry at home without supervision.